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Cheers! Webb finds complex organic molecules (COMs), such as ethanol and other icy ingredients for worlds, in early-stage protostars

An international team of astronomers using the NASA/ESA/CSA James Webb Space Telescope have discovered a variety of molecules, ranging from relatively simple ones like methane to complex compounds like acetic acid and ethanol, in early-stage protostars where planets have not yet formed. These are key ingredients for making potentially habitable worlds.

The presence of complex organic molecules (COMs) [1] in the solid phase in protostars was first predicted decades ago from laboratory experiments, and tentative detections of these molecules have been made by other space telescopes. This includes Webb’s Early Release Science Ice Age programme, which discovered diverse ices in the darkest, coldest regions of a molecular cloud measured to date.

A region of a molecular cloud. The cloud is dense and bright close to the top of the image, like rolling clouds, and grows darker and more wispy towards the bottom and in the top corner. One bright star, and several dimmer stars, are visible as light spots among the clouds. The image is a single exposure which has been assigned an orange colour for visibility. — This image was taken by Webb’s Mid-InfraRed Instrument (MIRI) of a region parallel to the massive protostar known as IRAS23385.
IRAS 2A and IRAS23385 (not visible in this image) were targets for a recent research effort by an international team of astronomers that used Webb to discover that the key ingredients for making potentially habitable worlds are present in early-stage protostars, where planets have not yet formed.
With MIRI’s unprecedented spectral resolution and sensitivity, the JOYS+ (James Webb Observations of Young ProtoStars) programme individually identified organic molecules that have been confirmed to be present in interstellar ices. This includes the robust detection of acetaldehyde, ethanol, methyl formate, and likely acetic acid, in the solid phase.
Credit: ESA/Webb, NASA, CSA, W. Rocha et al. (Leiden University)

Now, with the unprecedented spectral resolution and sensitivity of Webb’s Mid-InfraRed Instrument (MIRI), as part of the JOYS+ (James Webb Observations of Young ProtoStars) programme, these COMs have been individually identified and confirmed to be present in the interstellar ices. This includes the robust detection of acetaldehyde, ethanol (what we call alcohol), methyl formate, and likely acetic acid (the acid in vinegar), in the solid phase.

“This finding contributes to one of the long-standing questions in astrochemistry,” said team leader Will Rocha of Leiden University in the Netherlands. “What is the origin of COMs in space? Are they made in the gas phase or in ices? The detection of COMs in ices suggests that solid-phase chemical reactions on the surfaces of cold dust grains can build complex kinds of molecules.”

An international team of scientists using the NASA/ESA/CSA James Webb Space Telescope has identified a wealth of complex, carbon-containing (organic) molecules surrounding two protostars. This graphic shows the spectrum of one of the two protostars, IRAS 2A. It includes the fingerprints of acetaldehyde, ethanol, methylformate, and likely acetic acid, in the solid phase. These and other molecules detected there by Webb represent key ingredients for making potentially habitable worlds.Credit: NASA, ESA, CSA, L. Hustak (STScI) — An international team of scientists using the NASA/ESA/CSA James Webb Space Telescope has identified a wealth of complex, carbon-containing (organic) molecules surrounding two protostars. This graphic shows the spectrum of one of the two protostars, IRAS 2A. It includes the fingerprints of acetaldehyde, ethanol, methylformate, and likely acetic acid, in the solid phase. These and other molecules detected there by Webb represent key ingredients for making potentially habitable worlds.
Credit: NASA, ESA, CSA, L. Hustak (STScI)

As several COMs, including those detected in the solid phase in this research, were previously detected in the warm gas phase, it is now believed that they originate from the sublimation of ices. Sublimation is to change directly from a solid to a gas without becoming a liquid. Therefore, detecting COMs in ices makes astronomers hopeful about developing an improved understanding of the origins of other even larger molecules in space.

Harold Linnartz [2] led the Laboratory for Astrophysics in Leiden over many years and coordinated the measurements of the data used in this study. Ewine van Dishoeck of Leiden University, one of the coordinators of the JOYS+ programme, shared,

“Harold was particularly happy that in the COM assignments lab work could play an important role as it has been a long time getting here.”

Scientists are also keen to explore to what extent these COMs are transported to planets at much later stages in the evolution of the protostar. COMs in ices are transported more efficiently into planet-forming discs than gas from clouds. These icy COMs can therefore be inherited by comets and asteroids which in turn may collide with planets in formation. In that scenario COMs can be delivered to those planets, potentially providing the ingredients for life to flourish.

The science team also detected simpler molecules, including methane, formic acid (which makes the sting of ants painful), sulphur dioxide, and formaldehyde. Sulphur dioxide in particular allows the team to investigate the sulphur budget available in protostars. In addition, it is of prebiotic interest because existing research suggests that sulphur-containing compounds played an important role in driving metabolic reactions on the primitive Earth. Negative ions were also detected [3]; they form part of salts that are crucial for developing further chemical complexity at higher temperatures. This indicates that the ices may be much more complex and require further research.

Of particular interest is that one of the sources investigated, IRAS 2A, is characterised as a low-mass protostar. IRAS 2A may therefore have similarities with the primordial stages of our own Solar System. If that is the case, the chemical species identified in this protostar may have been present in the first stages of development of our Solar System and were later delivered to the primitive Earth.

All of these molecules can become part of comets and asteroids and eventually new planetary systems when the icy material is transported inward to the planet-forming discs as the protostellar system evolves,” said van Dishoeck. “We look forward to following this astrochemical trail step by step with more Webb data in the coming years.”

Other recent work by Pooneh Nazari of Leiden Observatory also raises astronomers’ hopes for finding more complexity in ices, following the tentative detections of methyl cyanide and ethyl cyanide from Webb NIRSpec data. Nazari says,

“It is impressive how Webb now allows us to further probe the ice chemistry down to the level of cyanides, important ingredients in prebiotic chemistry.”

Notes

[1] A molecule is a particle made up of two or more atoms that are held together by chemical bonds. A complex organic molecule is a molecule with multiple carbon atoms.

[2] These results are dedicated to team member Professor Harold Linnartz, who unexpectedly passed away in December 2023, shortly after the acceptance of this paper. Linnartz made significant contributions to the study of gaseous and icy molecules in space. He was the Director of the Leiden Laboratory for Astrophysics and many of the ice-phase spectra of simple and complex molecules used in this research were collected by students under his supervision. Linnartz was thrilled with the quality of the Webb data and the significance of these results for astrochemistry.

[3] An ion is an atom or molecule that has an overall electrical charge, resulting from an excess or deficit in the number of negative electrons compared to the number of positive protons in the ion. A negative ion is an ion with a net negative charge (so a surplus of electrons).

Press release from ESA Webb.

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Webb Unveils Dark Side of Pre-stellar Ice Chemistry

The discovery of diverse ices in the darkest, coldest regions of a molecular cloud measured to date has been announced by an international team of astronomers using the NASA/ESA/CSA James Webb Space Telescope. This result allows astronomers to examine the simple icy molecules that will be incorporated into future exoplanets, while opening a new window on the origin of more complex molecules that are the first step in the creation of the building blocks of life.

If you want to build a habitable planet, ices are a vital ingredient as they are the main carriers of several key light elements — namely carbon, hydrogen, oxygen, nitrogen, and sulphur (referred to collectively as CHONS). These elements are important ingredients in both planetary atmospheres and molecules like sugars, alcohols, and simple amino acids. In our Solar System, it is thought they were delivered to Earth’s surface by impacts with icy comets or asteroids. Furthermore, astronomers believe such ices were most likely already present in the dark cloud of cold dust and gas that would eventually collapse to make the Solar System. In these regions of space, icy dust grains provide a unique setting for atoms and molecules to meet, which can trigger chemical reactions that form very common substances like water. Detailed laboratory studies have further shown that some simple prebiotic molecules can form under these icy conditions.

Now an in-depth inventory of the deepest, coldest ices measured to date in a molecular cloud [1] has been announced by an international team of astronomers using the NASA/ESA/CSA James Webb Space Telescope. In addition to simple ices like water, the team was able to identify frozen forms of a wide range of molecules, from carbonyl sulfide, ammonia, and methane, to the simplest complex organic molecule, methanol (in the interstellar medium, organic molecules are considered to be complex when having six or more atoms). This is the most comprehensive census to date of the icy ingredients available to make future generations of stars and planets, before they are heated during the formation of young stars. These icy grains grow in size as they are funnelled into the protoplanetary discs of gas and dust around these young stars, essentially allowing astronomers to study all the potential icy molecules that will be incorporated into future exoplanets.

“Our results provide insights into the initial, dark chemistry stage of the formation of ice on the interstellar dust grains that will grow into the centimetre-sized pebbles from which planets form in discs,” said Melissa McClure, an astronomer at Leiden Observatory who is the principal investigator of the observing program and lead author of the paper describing this result. “These observations open a new window on the formation pathways for the simple and complex molecules that are needed to make the building blocks of life.”

In addition to the identified molecules, the team found evidence for prebiotic molecules more complex than methanol in these dense cloud ices, and, although they didn’t definitively attribute these signals to specific molecules, this proves for the first time that complex molecules form in the icy depths of molecular clouds before stars are born.

“Our identification of complex organic molecules, like methanol and potentially ethanol, also suggests that the many star and planet systems developing in this particular cloud will inherit molecules in a fairly advanced chemical state,” added Will Rocha, an astronomer at Leiden Observatory who contributed to this discovery. “This could mean that the presence of prebiotic molecules in planetary systems is a common result of star formation, rather than a unique feature of our own Solar System.”

By detecting the sulfur-bearing ice carbonyl sulfide, the researchers were able to estimate the amount of sulfur embedded in icy pre-stellar dust grains for the first time. While the amount measured is larger than previously observed, it is still less than the total amount expected to be present in this cloud, based on its density. This is true for the other CHONS elements as well. A key challenge for astronomers is understanding where these elements are hiding: in ices, soot-like materials, or rocks. The amount of CHONS in each type of material determines how much of these elements end up in exoplanet atmospheres and how much in their interiors.

“The fact that we haven’t seen all of the CHONS that we expect may indicate that they are locked up in more rocky or sooty materials that we cannot measure,” explained McClure. “This could allow a greater diversity in the bulk composition of terrestrial planets.”

Webb Unveils Dark Side of Pre-stellar Ice Chemistry. Astronomers have taken an inventory of the most deeply embedded ices in a cold molecular cloud to date. They used light from a background star, named NIR38, to illuminate the dark cloud called Chameleon I. Ices within the cloud absorbed certain wavelengths of infrared light, leaving spectral fingerprints called absorption lines. These lines indicate which substances are present within the molecular cloud.
These graphs show spectral data from three of the James Webb Space Telescope’s instruments. In addition to simple ices like water, the science team was able to identify frozen forms of a wide range of molecules, from carbon dioxide, ammonia, and methane, to the simplest complex organic molecule, methanol.
In addition to the identified molecules, the team found evidence for prebiotic molecules more complex than methanol (indicated in the lower-right panel). Although they didn’t definitively attribute these signals to specific molecules, this proves for the first time that complex molecules form in the icy depths of molecular clouds before stars are born.
The upper panels and lower-left panel all show the background star’s brightness versus wavelength. A lower brightness indicates absorption by ices and other materials in the molecular cloud. The lower-right panel displays the optical depth, which is essentially a logarithmic measure of how much light from the background star gets absorbed by the ices in the cloud. It is used to highlight weaker spectral features of less abundant varieties of ice.
Credit:
NASA, ESA, CSA, and J. Olmsted (STScI), M. K. McClure (Leiden Observatory), K. Pontoppidan (STScI), N. Crouzet (Leiden University), and Z. Smith (Open University)

The ices were detected and measured by studying how starlight from beyond the molecular cloud was absorbed by icy molecules at specific infrared wavelengths visible to Webb. This process leaves behind chemical fingerprints known as absorption spectra which can be compared with laboratory data to identify which ices are present in the molecular cloud. In this study, the team targeted ices buried in a particularly cold, dense and difficult to investigate region of the Chameleon I molecular cloud, a region 631 light-years from Earth which is currently in the process of forming dozens of young stars.

“We simply couldn’t have observed these ices without Webb,” elaborated Klaus Pontoppidan, Webb project scientist at the Space Telescope Science Institute, who was involved in this research. “The ices show up as dips against a continuum of background starlight. In regions that are this cold and dense, much of the light from the background star is blocked and Webb’s exquisite sensitivity was necessary to detect the starlight and therefore identify the ices in the molecular cloud.”

This research forms part of the Ice Age project, one of Webb’s 13 Early Release Science programs. These observations are designed to showcase Webb’s observing capabilities and allow the astronomical community to learn how to get the best from its instruments. The Ice Age team have already planned further observations, and hope to trace out the journey of ices from their formation through to the assemblage of icy comets.

“This is just the first in a series of spectral snapshots that we will obtain to see how the ices evolve from their initial synthesis to the comet-forming regions of protoplanetary discs,” concluded McClure. “This will tell us which mixture of ices — and therefore which elements — can eventually be delivered to the surfaces of terrestrial exoplanets or incorporated into the atmospheres of giant gas or ice planets.”

Webb Ice Chemistry — Webb Unveils Dark Side of Pre-stellar Ice Chemistry. This image by the NASA/ESA/CSA James Webb Space Telescope’s Near-InfraRed Camera (NIRCam) features the central region of the Chameleon I dark molecular cloud, which resides 630 light years away. The cold, wispy cloud material (blue, centre) is illuminated in the infrared by the glow of the young, outflowing protostar Ced 110 IRS 4 (orange, upper left). The light from numerous background stars, seen as orange dots behind the cloud, can be used to detect ices in the cloud, which absorb the starlight passing through them.
An international team of astronomers has reported the discovery of diverse ices in the darkest, coldest regions of a molecular cloud measured to date by studying this region. This result allows astronomers to examine the simple icy molecules that will be incorporated into future exoplanets, while opening a new window on the origin of more complex molecules that are the first step in the creation of the building blocks of life.
The two background stars used in this study, NIR38 and J110621 are denoted on the image in white.
Credit:
NASA, ESA, CSA, and M. Zamani (ESA/Webb); Science: F. Sun (Steward Observatory), Z. Smith (Open University), and the Ice Age ERS Team

Notes

[1] A molecular cloud is a vast interstellar cloud of gas and dust in which molecules can form, such as hydrogen and carbon monoxide. Cold, dense clumps in molecular clouds with higher densities than their surroundings can be the sites of star formation if these clumps collapse to form protostars.

Press release from ESA Webb

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