Astronomy

Tungsten found in Tycho Brahe’s alchemy laboratory, Uraniborg

By ScientifiCult 25 July 2024

Chemical analyses find hidden elements (such as tungsten) from renaissance astronomer Tycho Brahe’s alchemy laboratory, Uraniborg

Tycho Brahe was most famous for his contributions to astronomy. However, he also had a well-equipped alchemical laboratory where he produced secret medicines for Europe’s elite.

Tycho Brahe’s alchemy laboratory, Uraniborg Tycho Brahe receives Jacob VI of Scotland at Uraniborg, Credits: Royal Library, Denmark — Chemical analyses find hidden elements (such as tungsten) from renaissance astronomer Tycho Brahe’s alchemy laboratory, Uraniborg. In the picture, Tycho Brahe receives Jacob VI of Scotland at Uraniborg, Credits: Royal Library, Denmark

In the Middle Ages, alchemists were notoriously secretive and didn’t share their knowledge with others. Danish Tycho Brahe was no exception. Consequently, we don’t know precisely what he did in the alchemical laboratory located beneath his combined residence and observatory, Uraniborg, on the now Swedish island of Ven.

Only a few of his alchemical recipes have survived, and today, there are very few remnants of his laboratory. Uraniborg was demolished after his death in 1601, and the building materials were scattered for reuse.

However, during an excavation in 1988-1990, some pottery and glass shards were found in Uraniborg’s old garden. These shards were believed to originate from the basement’s alchemical laboratory. Five of these shards—four glass and one ceramic—have now undergone chemical analyses to determine which elements the original glass and ceramic containers came into contact with.

The chemical analyses were conducted by Professor Emeritus and expert in archaeometry, Kaare Lund Rasmussen from the Department of Physics, Chemistry, and Pharmacy, University of Southern Denmark. Senior researcher and museum curator Poul Grinder-Hansen from the National Museum of Denmark oversaw the insertion of the analyses into historical context.

Enriched levels of trace elements were found on four of them, while one glass shard showed no specific enrichments. The study has been published in the journal Heritage Science (link to be provided).

“Most intriguing are the elements found in higher concentrations than expected—indicating enrichment and providing insight into the substances used in Tycho Brahe’s alchemical laboratory”, said Kaare Lund Rasmussen.

The enriched elements are nickel, copper, zinc, tin, antimony, tungsten, gold, mercury, and lead, and they have been found on either the inside or outside of the shards.

Most of them are not surprising for an alchemist’s laboratory. Gold and mercury were – at least among the upper echelons of society – commonly known and used against a wide range of diseases.

“But tungsten is very mysterious. Tungsten had not even been described at that time, so what should we infer from its presence on a shard from Tycho Brahe’s alchemy workshop?”, said Kaare Lund Rasmussen.

Tungsten was first described and produced in pure form more than 180 years later by the Swedish chemist Carl Wilhelm Scheele. Tungsten occurs naturally in certain minerals, and perhaps the element found its way to Tycho Brahe’s laboratory through one of these minerals. In the laboratory, the mineral might have undergone some processing that separated the tungsten, without Tycho Brahe ever realizing it.

However, there is also another possibility that Professor Kaare Lund Rasmussen emphasizes has no evidence whatsoever – but which could be plausible.

Already in the first half of the 1500s, the German mineralogist Georgius Agricola described something strange in tin ore from Saxony, which caused problems when he tried to smelt tin. Agricola called this strange substance in the tin ore “Wolfram” (German for Wolf’s froth, later renamed to tungsten in English).

“Maybe Tycho Brahe had heard about this and thus knew of tungsten’s existence. But this is not something we know or can say based on the analyses I have done. It is merely a possible theoretical explanation for why we find tungsten in the samples”, said Kaare Lund Rasmussen.

Tycho Brahe belonged to the branch of alchemists who, inspired by the German physician Paracelsus, tried to develop medicine for various diseases of the time: plague, syphilis, leprosy, fever, stomach aches, etc. But he distanced himself from the branch that tried to create gold from less valuable minerals and metals.

In line with the other medical alchemists of the time, he kept his recipes close to his chest and shared them only with a few selected individuals, such as his patron, Emperor Rudolph II, who allegedly received Tycho Brahe’s prescriptions for plague medicine.

We know that Tycho Brahe’s plague medicine was complicated to produce. It contained theriac, which was one of the standard remedies for almost everything at the time and could have up to 60 ingredients, including snake flesh and opium. It also contained copper or iron vitriol (sulphates), various oils, and herbs.

After various filtrations and distillations, the first of Brahe’s three recipes against plague was obtained. This could be made even more potent by adding tinctures of, for example, coral, sapphires, hyacinths, or potable gold.

“It may seem strange that Tycho Brahe was involved in both astronomy and alchemy, but when one understands his worldview, it makes sense. He believed that there were obvious connections between the heavenly bodies, earthly substances, and the body’s organs. Thus, the Sun, gold, and the heart were connected, and the same applied to the Moon, silver, and the brain; Jupiter, tin, and the liver; Venus, copper, and the kidneys; Saturn, lead, and the spleen; Mars, iron, and the gallbladder; and Mercury, mercury, and the lungs. Minerals and gemstones could also be linked to this system, so emeralds, for example, belonged to Mercury”, explained Poul Grinder-Hansen.

Kaare Lund Rasmussen has previously analyzed hair and bones from Tycho Brahe and found, among other elements, gold. This could indicate that Tycho Brahe himself had taken medicine that contained potable gold.

Bibliographic information:

Chemical analysis of fragments of glass and ceramic ware from Tycho Brahe’s laboratory at Uraniborg on the island of Ven (Sweden), Heritage Science (25-Jul-2024)

Press release from the University of Southern Denmark, by Birgitte Svennevig.

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Biology

Earliest Ichthyosaur from Age of Dinosaurs found on the Arctic island of Spitsbergen

By ScientifiCult 14 March 2023

Earliest Ichthyosaur from Age of Dinosaurs found on the Arctic island of Spitsbergen

For nearly 190 years, scientists have searched for the origins of ancient sea-going reptiles from the Age of Dinosaurs. Now a team of Swedish and Norwegian palaeontologists has discovered remains of the earliest known ichthyosaur or ‘fish-lizard’ on the remote Arctic island of Spitsbergen.

Ichthyosaurs were an extinct group of marine reptiles whose fossils have been recovered worldwide. They were amongst the first land living animals to adapt to life in the open sea, and evolved a ‘fish-like’ body shape similar to modern whales. Ichthyosaurs were at the top of the food chain in the oceans while dinosaurs roamed the land, and dominated marine habitats for over 160 million years.

Reconstruction of the earliest ichthyosaur and the 250-million-year-old ecosystem found on Spitsbergen. Credits: Illustration: Esther van Hulsen

According to the textbooks, reptiles first ventured into the open sea after the end-Permian mass extinction, which devastated marine ecosystems and paved the way for the dawn of the Age of Dinosaurs nearly 252 million years ago. As the story goes, land-based reptiles with walking legs invaded shallow coastal environments to take advantage marine predator niches that were left vacant by this cataclysmic event.

Computed tomography image and cross-section showing internal bone structure of vertebrae from the earliest ichthyosaur. Credits: Øyvind Hammer and Jørn Hurum

Over time, these early amphibious reptiles became more efficient at swimming and eventually modified their limbs into flippers, developed a ‘fish-like’ body shape, and started giving birth to live young; thus, severing their final tie with the land by not needing to come ashore to lay eggs.The new fossils discovered on Spitsbergen are now revising this long accepted theory.

Animal remains on the ancient seabed

Close to the hunting cabins on the southern shore of Ice Fjord in western Spitsbergen, Flower’s valley cuts through snow-capped mountains exposing rock layers that were once mud at the bottom of the sea around 250 million years ago. A fast-flowing river fed by snow melt has eroded away the mudstone to reveal rounded limestone boulders called concretions.

These formed from limey sediments that settled around decomposing animal remains on the ancient seabed, subsequently preserving them in spectacular three-dimensional detail. Paleontologists today hunt for these concretions to examine the fossil traces of long-dead sea creatures.

Fossil-bearing rocks on Spitsbergen that produce the earliest ichthyosaur remains. Credits: Benjamin Kear

During an expedition in 2014, a large number of concretions were collected from Flower’s valley and shipped back to the Natural History Museum at the University of Oslo for future study. Research conducted with The Museum of Evolution at Uppsala University has now identified bony fish and bizarre ‘crocodile-like’ amphibian bones, together with 11 articulated tail vertebrae from an ichthyosaur.

Unexpectedly, these vertebrae occurred within rocks that were supposedly too old for ichthyosaurs. Also, rather than representing the textbook example of an amphibious ichthyosaur ancestor, the vertebrae are identical to those of geologically much younger larger-bodied ichthyosaurs, and even preserve internal bone microstructure showing adaptive hallmarks of fast growth, elevated metabolism and a fully oceanic lifestyle.

Before the beginning of the Age of Dinosaurs

Geochemical testing of the surrounding rock confirmed the age of the fossils at approximately two million years after the end-Permian mass extinction. Given the estimated timescale of oceanic reptile evolution, this pushes back the origin and early diversification of ichthyosaurs to before the beginning of the Age of Dinosaurs; thereby forcing a revision of the textbook interpretation and revealing that ichthyosaurs probably first radiated into marine environments prior to the extinction event.

”Excitingly, the discovery of the oldest ichthyosaur rewrites the popular vision of Age of Dinosaurs as the emergence timeframe of major reptile lineages. It now seems that at least some groups predated this landmark interval, with fossils of their most ancient ancestors still awaiting discovery in even older rocks on Spitsbergen and elsewhere in the world,” says Benjamin Kear, researcher at Museum of Evolution, Uppsala University.

Bibliographic information:

Kear, B.P., Engelschiøn, V.S., Hammer, Ø., Roberts, A.J. & Hurum, J.H., 2023: Earliest Triassic ichthyosaur fossils push back oceanic reptile origins. Current Biology 33(5), R1-R2. DOI: 10.1016/j.cub.2022.12.053

Press release from Uppsala University, by Linda Koffmar.

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Genetics

Discovery of world’s oldest DNA breaks record by one million years

By ScientifiCult 7 December 2022

A new chapter in the history of evolution

Discovery of world’s oldest DNA breaks record by one million years

Two-million-year-old DNA has been identified for the first time opening a new chapter in the history of evolution.

Microscopic fragments of environmental DNA were found in Ice Age sediment in northern Greenland. The fragments are one million years older than the previous record for DNA sampled from a Siberian mammoth bone.

The ancient DNA has been used to map a two-million-year-old ecosystem which weathered extreme climate change. The results could help predict the long-term environmental toll of today’s global warming.

The discovery was made by a team of scientists led by Professor Eske Willerslev and Professor Kurt Kjær. Professor Willerslev is a Fellow of St John’s College, University of Cambridge and Director of the Lundbeck Foundation GeoGenetics Centre at the University of Copenhagen where Professor Kjær, a geology expert, is also based.

The results of the 41 usable samples found hidden in clay and quartz are published today in Nature.

“A new chapter spanning one million extra years of history has finally been opened and for the first time we can look directly at the DNA of a past ecosystem that far back in time,” says Willerslev.

“DNA can degrade quickly but we’ve shown that under the right circumstances, we can now go back further in time than anyone could have dared imagine.”

“The ancient DNA samples were found buried deep in sediment that had built-up over 20,000 years,” says Kjær. “The sediment was eventually preserved in ice or permafrost and, crucially, not disturbed by humans for two million years.”

Close-up of organic material in the coastal deposits. The organic layers show traces of the rich plant flora and insect fauna that lived two million years ago in Kap København in North Greenland. Credits: Professor Kurt H. Kjær

The incomplete samples, a few millionths of a millimetre long, were taken from the København Formation, a sediment deposit almost 100 metres thick tucked in the mouth of a fjord in the Arctic Ocean in Greenland’s northernmost point. The climate in Greenland at the time varied between Arctic and temperate and was between 10-17C warmer than Greenland is today. The sediment built up metre by metre in a shallow bay.

Evidence of animals, plants and microorganisms including reindeer, hares, lemmings, birch and poplar trees were discovered. Researchers even found that Mastodon, an Ice Age mammal, roamed as far as Greenland before later becoming extinct. Previously it was thought the range of the elephant-like animals did not extend as far as Greenland from its known origins of North and Central America.

Detective work by 40 researchers from Denmark, the UK, France, Sweden, Norway, the USA and Germany, unlocked the secrets of the fragments of DNA. The process was painstaking – first they needed to establish whether there was DNA hidden in the clay and quartz, and if there was, could they successfully detach the DNA from the sediment to examine it? The answer, eventually, was yes. The researchers compared every single DNA fragment with extensive libraries of DNA collected from present-day animals, plants and microorganisms. A picture began to emerge of the DNA from trees, bushes, birds, animals and microorganisms.

A two million- year-old trunk from a larch tree still stuck in the permafrost within the coastal deposits. The tree was carried to the sea by the rivers that eroded the former forested landscape. Credits: Professor Svend Funder

Some of the DNA fragments were easy to classify as predecessors to present-day species, others could only be linked at genus level, and some originated from species impossible to place in the DNA libraries of animals, plants and microorganisms still living in the 21st century.

The two-million-year-old samples also help academics build a picture of a previously unknown stage in the evolution of the DNA of a range of species still in existence today.

“Expeditions are expensive and many of the samples were taken back in 2006 when the team were in Greenland for another project, they have been stored ever since,” says Kjær.

“It wasn’t until a new generation of DNA extraction and sequencing equipment was developed that we’ve been able to locate and identify extremely small and damaged fragments of DNA in the sediment samples. It meant we were finally able to map a two-million-year-old ecosystem.”

“The Kap København ecosystem, which has no present-day equivalent, existed at considerably higher temperatures than we have today – and because, on the face of it, the climate seems to have been similar to the climate we expect on our planet in the future due to global warming,” says co-first author Assistant Professor Mikkel Pedersen of the Lundbeck Foundation GeoGenetics Centre.

“One of the key factors here is to what degree species will be able to adapt to the change in conditions arising from a significant increase in temperature. The data suggests that more species can evolve and adapt to wildly varying temperatures than previously thought. But, crucially, these results show they need time to do this. The speed of today’s global warming means organisms and species do not have that time so the climate emergency remains a huge threat to biodiversity and the world – extinction is on the horizon for some species including plants and trees.”

While reviewing the ancient DNA from the Kap København Formation, the researchers also found DNA from a wide range of microorganisms, including bacteria and fungi, which they are continuing to map. A detailed description of how the interaction – between animals, plants and single-cell organisms – within the former ecosystem at Greenland’s northernmost point worked biologically will be presented in a future research paper.

It is now hoped that some of the ‘tricks’ of the two-million-year-old plant DNA discovered may be used to help make some endangered species more resistant to a warming climate.

“It is possible that genetic engineering could mimic the strategy developed by plants and trees two million years ago to survive in a climate characterised by rising temperatures and prevent the extinction of some species, plants and trees,” says Kjær. “This is one of the reasons this scientific advance is so significant because it could reveal how to attempt to counteract the devastating impact of global warming.”

The findings from the Kap København Formation in Greenland have opened up a whole new period in DNA detection.

“DNA generally survives best in cold, dry conditions such as those that prevailed during most of the period since the material was deposited at Kap København,” says Willerslev. “Now that we have successfully extracted ancient DNA from clay and quartz, it may be possible that clay may have preserved ancient DNA in warm, humid environments in sites found in Africa.

“If we can begin to explore ancient DNA in clay grains from Africa, we may be able to gather ground-breaking information about the origin of many different species – perhaps even new knowledge about the first humans and their ancestors – the possibilities are endless.”

Bibliographic information:

A 2-million-year-old ecosystem in Greenland uncovered by environmental DNA, Nature (7-Dec-2022), DOI: 10.1038/s41586-022-05453-y

Press release from the University of Cambridge on the discovery of world’s oldest DNA.

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